Model Studies Towards Azadirachtin: Part 2. Construction of the Crowded C8bC14 Bond by Transition Metal Chemistry We thank Drs. D. H. Huang and G. Siuzdak for NMR spectroscopic and mass spectrometric assistance, respectively. This work was financially supported by the National Institutes of Health (USA), the Skaggs Institute for Chemical Biology, a predoctoral fellowship from the Division of Organic Chemistry of the American Chemical Society sponsored by Novartis (to A.J.R.), postdoctoral fellowships from Bayer AG (to M.F.), and Association pour la Recherche sur le Cancer (to R.B.), and grants from Abbott Laboratories, ArrayBiopharma, Bayer, Boehringer Ingelheim, DuPont, Glaxo, Hoffmann-LaRoche, Merck, Novartis, Pfizer, and Schering Plough.

2002 ◽  
Vol 114 (12) ◽  
pp. 2211 ◽  
Author(s):  
K. C. Nicolaou ◽  
A. J. Roecker ◽  
Markus Follmann ◽  
Rachid Baati
Keyword(s):  
Organic Chemistry ◽  
Transition Metal ◽  
Chemical Biology ◽  
American Chemical Society ◽  
Chemical Society ◽  
Mass Spectrometric ◽  
National Institutes Of Health ◽  
Transition Metal Chemistry ◽  
Metal Chemistry ◽  
Model Studies

scholarly journals Alkene Difunctionalization Using Hypervalent Iodine Reagents: Progress and Developments in the Past Ten Years

Molecules ◽  
2019 ◽  
Vol 24 (14) ◽  
pp. 2634 ◽  
Author(s):  
Lee ◽  
Choi ◽  
Hong
Keyword(s):  
Organic Chemistry ◽  
Transition Metal ◽  
Hypervalent Iodine ◽  
Transition Metal Chemistry ◽  
Metal Chemistry ◽  
The Past ◽  
Catalytic Asymmetric ◽  
Alkene Difunctionalization

Hypervalent iodine reagents are of considerable relevance in organic chemistry as they can provide a complementary reaction strategy to the use of traditional transition metal chemistry. Over the past two decades, there have been an increasing number of applications including stoichiometric oxidation and catalytic asymmetric variations. This review outlines the main advances in the past 10 years in regard to alkene heterofunctionalization chemistry using achiral and chiral hypervalent iodine reagents and catalysts.

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